Guo-Liang Xu,Zi Zhen,Yi-Sheng Shi,Kang-Xian Guo,E Feddi,Jian-Hui Yuan and Zhi-Hai Zhang,??

1 School of Physics and Electronics,Yancheng Teachers University,Yancheng 224002,China

2 Department of Physics,College of Physics and Electronic Engineering,Guangzhou University,Guangzhou 510006,China

3 Laboratoire de la matière condensée et Sciences Interdisciplinaires(LAMCScI),Group of Optoelectronic of Semiconductors and Nanomaterials,ENSET,Mohammed V University in Rabat,Morocco

4 Laboratory of Biomedical Photonics and Engineering,Guangxi Medical University,Nanning 530021,China

Abstract In this study,the effects of hydrostatic pressure and temperature on nonlinear optical rectification(OR),second-harmonic generation(SHG),third-harmonic generation(THG)and the linear,nonlinear,and total optical absorption coefficients(OACs)of a semiparabolic plus semi-inverse squared quantum well(QW)are theoretically investigated.The results show that hydrostatic pressure and temperature have significant effects on the optical properties of semiparabolic plus semi-inverse squared QWs,and that the energy levels and magnitudes of the resonant peaks of OR,SHG,THG,and the total OACs vary according to the shape of the limiting potential,the hydrostatic pressure,and the temperature.It is easily seen that the peak positions of the resonant peaks of OR,SHG,THG,and the total OACs in the semiparabolic plus semi-inverse squared QW show a red shift with increasing hydrostatic pressure,but a blue shift with increasing temperature.Therefore,the magnitude and position of the resonant peaks of OR,SHG,THG,and the total OACs can be adjusted by changing the hydrostatic pressure and the temperature,which promise a new degree of freedom in the tunability of various electro-optical devices.

Keywords:Quantum well,Optical properties,Hydrostatic pressure,Temperature

1.Introduction

In recent years,due to the development of sophisticated growth techniques such as e-beam lithography,reactive ion etching,metal organic chemical vapor deposition and molecular beam epitaxy,the fabrication of artificial low-dimensional semiconductor nanostructures has become feasible[1–4].Lowdimensional semiconductor nanostructures such as quantum wells(QW),quantum wires,and quantum dots have attracted remarkable attention,from both fundamental and technological points of view.These nanostructures lie between the molecular material and the bulk material.The simultaneous strong quantum confinement of carriers and layering of structures produce not only quantitative but also qualitative differences in physics compared to the the bulk structures,which result in the formation of discrete energy sub-bands that are conducive to drastic changes in the electronic and optical properties.Among these nanostructures,QWs are an integral part of many electronic and optoelectronic devices,because they are easier to grow and fabricate in devices with larger bandgaps and can enhance the strength of electro-optical interactions by confining carriers to small regions.Thus,the optical and electrical properties of these QWs offer a wide range of potential applications in high-performance optical devices such as laser diodes,light-emitting diodes,laser amplifiers,photo-detectors,high-speed electrooptical modulators,and so on[5–7].

In the study of low-dimensional systems,one of the most interesting properties to explore is the influence of spatial confinement on the energy spectra and nonlinear optical properties of a QW system.Most experimental and theoretical investigations have examined the effects of the shape,size,and confining potential in QW systems,which have provided great advantages in terms of tuning the desired optical properties.Chen et al theoretically studied nonlinear optical rectification(OR)in double triangular QWs.The results showed that the theoretical value of OR was 2?3 orders of magnitude higher that in a single QW system[8].H.Hassanabadi et al reported nonlinear OR and second-harmonic generation(SHG)in semiparabolic and semi-inverse squared QWs,and confirmed that the magnitudes of both the OR coefficients and the SHG susceptibility decreased and increased with an increase in the confinement frequency ω0and the geometric structural parameter β[9].S.?akiro?lu et al reported OR,SHG,and third-harmonic generation(THG)in a P?schl-Teller QW.The results showed that the peak positions were sensitive to the asymmetry parameters governing the confinement potential,and that the nonlinear OR and SHG susceptibility increased with an enhancement in the asymmetry of the QW;they also showed that the maximum asymmetry was be obtained using an optimized set of parameters[10].Z.M.Zhang et al studied the THG susceptibilities,the nonlinear optical absorption coefficients(OACs)and the refractive index changes(RICs)of a square tangent QW and confirmed that the THG susceptibilities,the OACs and the RICs were strongly affected by d and U0,which had great influence on the geometry of the QW[11].Consequently,the geometric structure factor greatly affects the electrical,optical,and transport behavior of QW systems.

Recently,investigation of the nonlinear optical properties of QWs together with various physical effects,such as hydrostatic pressure,temperature,external electric,and magnetic fields,and so on,has been the topic of many theoretical and experimental studies,which have realized the effective adjustment of nonlinear optical properties.J.H.Yuan et al studied the effects of applied electric fields on the SHG in semiparabolic QWs.Their results indicated that an increase in the applied electric field can weaken the peak values of SHG,but that the nonlinear OR was strengthened[12].The influences of the applied magnetic field,temperature,and hydrostatic pressure on the nonlinear optical properties of a symmetric double semi-V-shaped QW were studied by U.Yesilgul et al[13].S.?akiro?lu calculated the linear and nonlinear OACs and RICs of Morse QWs under the influence of a static electric field[14].X.Liu et al reported the nonlinear OR and SHG in asymmetrical Gaussian QWs under the influence of applied magnetic fields,temperatures,and hydrostatic pressures[15].The nonlinear OR and SHG in a semiparabolic QW under the influence of an intense laser field along with applied electric and magnetic fields were theoretically studied by F.Ungan et al[16].S.?akiro?lu et al reported the effects of an intense laser field and an applied electric field on the nonlinear OACs and RICs in a Morse QW[17].According to these reports,it was found that not only the structural parameters but also the external physical fields have great influence on the optical characteristics of these structures.Such a system can be used to control and adjust the density output of semiconductor devices,which also provide the desired optical properties for device outlines.

The purpose of this work is to investigate the effects of hydrostatic pressure and temperature on the nonlinear optical properties of a semiparabolic plus semi-inverse squared QW,which have not yet been discussed.This paper is organized as follows:section 2 contains the details of the theoretical framework.The results and a discussion are presented in section 3.Finally,the conclusions are given in section 4.

2.Theory

In the framework of effective mass approximation,the Hamiltonian for GaAs/AlxGa1?xAs semiparabolic plus semiinverse squared QWs under the influence of hydrostatic pressure P and temperature T may be written as:

Here,m*(P,T)=(0.0665+0.0835x),m*(P,T)is the hydrostatic pressure-(P)and temperature-(T)dependent electron effective mass,the aluminum concentration is given by x=0.3,while for GaAs m*(z)=0.067m0(m0is the free electron mass),and V(z,P,T)is the semiparabolic plus semiinverse squared confining potential.They are given by[13,15,18,19]

The semiparabolic plus semi-inverse squared confining potential is given by

where ωzand β are the confinement frequency and the characteristic parameter of the inverse squared potential,respectively,which control the asymmetry degree of the potential well.Also,LPis the pressure-dependent characteristic size of the QW,which is obtained from the fractional change in the volume of the sample:LP=L[1?(1.16×10?3kbar?1?7.4×10?4kbar?1)P],where L is the original width of the confinement potentials in the z direction.

In this manuscript,we use the finite difference technique to obtain the numerical solution of the Schr?dinger equation(1)after the energies and the corresponding envelope wave functions have been obtained.The nonlinear optical properties for ORSHGTHGand the OACs α(ω,I)can be easily calculated using the compact density matrix method and the iterative procedure,which are given by[18–22]

The analytical forms of the linear and third-order nonlinear OACs are then given by

Therefore,the total absorption coefficient α(ω,I)is given by

where σνis the density of electrons in the QW,μij=|〈Ψi|z|Ψj〉|(i,j=0,1,2,3)is the off-diagonal matrix element,δ01=|μ11?μ00|,ω01is the transition frequency,μ is the permeability of the system,Eij=Ei?Ejis the energy interval between two different electronic states,I is the incident optical intensity,andΓk=1/Tkwith k=(0,1,2,3)are damping terms associated with the lifetime of the electrons involved in the transitions.

3.Results and discussion

In the numerical calculations for the AlxGa1?xAs/GaAs semiparabolic plus semi-inverse squared QW,the following material parameters are used[21–24]:L=10nm,nr=3.2,ε0=8.85×10?12Fm?1,ε=0,T0=0.14 ps,T1=1 ps,T2=0.2 ps,T12=0.5 ps,T23=0.12 ps,I=1×1010MW/cm2,Γ12=1/T12,and σν=5×1024m?3.

Initially,in order to show the effects of hydrostatic pressure P and temperature T on the confining potential,in figure 1(a)we present the variation of the potential shape for three different values of hydrostatic pressure,P=0,P=50 kbar,and P=100 kbar.It is clear from the figure that the well width decreases slightly with increasing hydrostatic pressure P,which leads to stronger confinement of the carriers,causing an enhancement of the energy differences E10,E20,and E30.In figure 1(b)we present the variation of the potential shape for three different temperature values,T=0,T=200 K,T=400 K,and find that the well width and well depth change very little as the temperature T increases.Therefore,the effect of temperature T on the confined potential is negligible.

Figures 2(a)and(b)show the variation of the energy eigenvalues E0,E1,E2,and E3and the energy differences E10,E20,and E30as a function of the hydrostatic pressure P and the temperature T with T=0 and P=0,respectively.As can be seen from figure 2(a),as the hydrostatic pressure P increases,the values of the conduction energy levels E0,E1,E2,and E3decrease monotonically.Moreover,the higher the energy level,the more sensitive the QW is to the variation of hydrostatic pressure P.This is the case because when the hydrostatic pressure P increases,the electron’s effective mass increases.Obviously,the influence of the hydrostatic pressure P on the effective mass is more dominant than that of the confined potential,which causes a reduction of the values of the conduction energy levels.Therefore,we can easily see that the energy differences E10,E20,and E30decrease when the hydrostatic pressure P increases.From figure 2(b),it can be seen that,as the temperature T increases,the values of the conduction energy levels E0,E1,E2,and E3increase.This is because the structural parameters such as the electron’s effective mass and the conduction band offset decrease with increasing temperature T.Moreover,the energy levels of the excited states change more obviously with temperature T,and the ground state increases a little with an increase in the temperature T.For this reason,the energy differences between the first excited state and the ground E10,the second excited state and the ground E20and the third excited state and the ground E30of the system increase as the temperature T increases.

Figure 1.Pictorial view of the confinement potential in a semiparabolic plus semi-inverse squared QW for two different variables:(a)hydrostatic pressure P and(b)temperature T.

Figure 2.The energy eigenvalues E0,E1,E2,and E3 and energy differences E10,E20,and E30 are plotted as a function of the(a)hydrostatic pressure P and(b)the temperature T,respectively.

Figure 3.The variation of nonlinear ORas a function of the photon energy for different hydrostatic pressures P(a),and temperatures T(b),respectively.

Figure 4.The variation of SHGas a function of photon energy for three different values of hydrostatic pressure P(a)and temperature T(b),respectively.

In figure 3,we can observe the behavior of the nonlinear OR,calculated as a function of the photon energy.Several distinct values of(a)hydrostatic pressure(P=0,50 kbar,100 kbar)with T=0 K,and(b)temperature(T=0,200 K,400 K)with P=0 kbar have been discussed,respectively.As can be seen from figure 3(a),the following points can be deduced:(1)the nonlinear ORcoefficient has a maximum(in any curve and for different hydrostatic pressures P)at a photon energy equal to the energy difference between the ground state and the first excited state E10,which is the resonant photon energy;(2)the amplitude of the resonant peak of nonlinear ORincreases with increasing hydrostatic pressure P.The physical reason for this behavior is that when the hydrostatic pressure P increases,the transition matrix element μ10increases because the electron’s effective mass and the conduction band offset increase with increasing P.Also,the positions of the resonant peaks shift toward lower energies(a red shift),because the energy difference E10decreases with increasing hydrostatic pressure P.This behavior is in agreement with figure 2(a).It can be seen from figure 3(b)that the amplitude of the resonant peak of nonlinear ORis directly related to the temperature T and decreases with an increase in the temperature T.The physical reason for this is a reduction of transition matrix element μ10because the electron’s effective mass and the conduction band offset decrease with an increase in temperature T.For this reason,the energy difference E10between the first excited state and the ground state of the system increases.Therefore,as the temperature T increases,the resonant peak positions of nonlinear OR shift toward higher energies.

Figure 4 shows the variations of the SHGas a function of photon energy for three different values of hydrostatic pressure P=0,P=50 kbar,and P=100 kbar(a)and temperature T=0,T=200 K,T=400 K(b),respectively.From figure 4(a),it can be seen that the SHGsusceptibility has two resonant peaks(in any curve and for different hydrostatic pressures P),where the photon energy is equal to the energy difference between the ground state and the first excited state E10and the energy difference between the ground state and the second excited state E20,which is the resonant photon energy.Meanwhile,the locations of the resonant peaks of SHGshift toward lower energies with increasing hydrostatic pressure P.Also,the amplitudes of the resonant peaks of SHGincrease when the hydrostatic pressure P increases.The physical origin of this behavior is that the electron’s effective mass and the quantum confinement effect increase.When the electron’s effective mass changes,the energy differences E10and E20and the overlaps of state also change.It can be seen from figure 4(b)that the resonant peak positions of SHGmove to higher energy regions when the temperature T increases.Also,the amplitudes of the resonant peaks of SHGdecrease with increasing temperature T.The physical origin of this behavior is the decrease of the electron’s effective mass and the conduction band offset when the temperature T increases.When the electron’s effective mass changes,the energy differences E10and E20and the overlaps of state also change.This is true with the exception of the cases depicted in figures 2(a)and(b).

Figure 5.The variation of THGas a function of the photon energy for three different values of hydrostatic pressure P(a)and temperature T(b),respectively.

Figure 6.The variation of the linear α(1),nonlinear α(3),and total OACs α as a function of the photon energy for three different values of hydrostatic pressure P(a)and temperature T(b),respectively.

The effects of hydrostatic pressure P and temperature T on the THGare plotted in figures 5(a)and(b),respectively.As can be seen from these figures,the following points can be deduced:(1)three different resonant peaks are seen in the THGspectrum,corresponding to one-photon resonance(E10=?ω),two-photon resonance(E20=2?ω),and three-photon resonance(E30=3?ω);(2)an increase in the hydrostatic pressure P results in a red shift of the THGspectrum.This is due to a decrease in the energy differences E10,E20,and E30(as shown in figure 2(a)).Also,the magnitudes of all resonant peaks increase with increasing hydrostatic pressure P,which illustrates the complex competitive coupling mechanisms caused by hydrostatic pressure P;(3)the larger the temperature T,the smaller the value of THGThe physical reason for this feature is that the electron’s effective mass and the overlaps between different electronic states reduce with increasing temperature T.Also,the positions of the resonant peaks of THGdisplay a blue shift when the temperature T increases.This is because the energy intervals E10,E20,and E30increase with an increase of the temperature T,which related to the fact that the electron’s effective mass and the conduction band offset decrease with temperature T(as shown in figure 2(b)).

In figure 6,the linear α(1),nonlinear α(3),and total OACs α are plotted as a function of the incident photon energy for three different values of hydrostatic pressure P=0,P=50 kbar,P=100 kbar and temperatures T=0,T=200 K,T=400 K,respectively.As can be seen in figure 6(a),the total OAC α is significantly reduced due to a nonlinear contribution with increasing hydrostatic pressure P,and the nonlinearity of α(3)should be considered when the intensity of the incoming radiation is strong enough,which leads to a reduction in the total absorption.In addition,the corresponding peak positions of the linear α(1),nonlinear α(3),and total OACs α undergo a red shift.This is because the electron’s effective mass increases with increasing hydrostatic pressure P,which reflects the competitive relationship between the kinetic and potential energies of the system(see figure 2(a)).From figure 6(b),we can see that,as an immediate effect of augmenting the magnitude of the temperature T,the amplitudes of the resonant peaks of the total OACs α present an increase in their heights or intensities.Also,the most notable effect is an obvious blue shift of the positions of the resonant peaks of the total OACs α with increasing temperature T.This shift is caused by the increased energy level distance when the temperature T changes(see figure 2(b)).

4.Conclusions

In this work,we have investigated the effects of hydrostatic pressure P and temperature T on the nonlinear ORSHGTHGand total OACs α of a semiparabolic plus semi-inverse squared QW using the finite difference method.The optical properties calculated within the framework of the compact density matrix approach and an iterative scheme were investigated for varying strengths of the hydrostatic pressure P and the temperature T.The numerical results revealed that an adjustment of the hydrostatic pressure P and the temperature T that govern the confining potential and the electron effective’s mass can lead to a change in the optical response of the system.However,the change to the electron’s effective mass caused by the hydrostatic pressure P and the temperature T plays an important role in the optical response of the system.Moreover,as the hydrostatic pressure P increases,the amplitudes of the resonant peaks of nonlinear ORSHGand THGincrease significantly.However,the amplitudes of the resonant peaks of the total OACs,α,changed inversely.In addition,a red shift in the peaks was obtained.With increasing temperature T,the resonant peaks of the nonlinear ORSHGand THGexperience an obvious blue shift,and the amplitudes of the resonant peaks of nonlinear ORSHGand THGdecrease significantly,which is contrary to the change of amplitude of the resonant peaks of the total OACs,α.We conclude that the hydrostatic pressure and temperature may serve as a probe for the controllability of the nonlinear optical properties of the QW.