MA Ji-Dong WU Yun-Mio JIANG Chun-Hi ZHANG Hou-An ZHU Jun-Qiu②

a (Fujian Key Laboratory of Functional Materials and Applications, Xiamen University of Technology, Xiamen 361024, China) b (School of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou 362000, China)

ABSTRACT A high capacitance RuO2-ZrO2 coating was prepared by thermal decomposition method. Extended X-ray absorption fine structure (EXAFS), X-ray diffraction (XRD), high-resolution transmission electron microscope (HRTEM) and ab initio calculations were applied to understand the role of the microstructure in the acquisition of high specific capacitance of RuO2-based oxides. The results show that the RuO2-ZrO2 oxide prepared at critical crystallization temperature can be considered to be quasi-amorphous or microcrystalline (A short-range ordered crystal structure can be seen from the TEM image, but no diffraction peaks can be seen from the XRD diffraction patterns). And this RuO2-ZrO2 was identified as a solid solution with high solid solubility. It referred to herein as a quasi-amorphous solid solution. Such a special microstructure was conducive for “synergistic catalysis” owing to the cationic interaction and thus could gain high “active site density” and high “active surface”, thus developing high specific capacitance.

Keywords: supercapacitor, quasi-amorphous, RuO2, ZrO2, synergistic catalysis;

1 INTRODUCTION

With metallic conductivity, excellent electrochemical stability and high theoretical specific capacitance, RuO2is recognized as one ideal electrode material for supercapacitor. However, due to agglomeration and low specific surface area, the expected high capacitance is difficult to be achieved on pure RuO2[1,2]. Instead, combining RuO2with other non-noble metal oxides has been proven to be an effective way to acquire high specific capacitance[3-6]. The added non-noble metal oxides can not only serve as the carrier to increase the dispersibility and electrochemical stability of RuO2, but can also generate “synergistic catalysis” effect to improve the electronic structure of RuO2[7,8]. Both effects are beneficial to activate the oxidization activity, and hence significantly increase the capacitance of RuO2. So far, TiO2, SnO2, Co3O4, Ta2O5, MnO2and SiO2have been used as the effective second components[9-12], although their exact roles on the improved capacitance are still in controversy.

In our previous work, the RuO2-ZrO2coating on Ti substrate was prepared by thermal decomposition method and an ultrahigh capacitance of 949 F·g-1was obtained at a critical temperature of about 290 ℃[13,14]. This high capacitance has been ascribed to the special amorphous structure of the RuO2-ZrO2coating in combination with short range order microcrystallines. However, a detailed microstructural interpre-tation was still lack. In general, the synergistic effect between the amorphous RuO2and the second component may play a key role in the high specific capacitance[10,12]. The amorphous structure can be normally divided into topology and microcrystal according to the degree of order. It can also be divided into amorphous, quasi-amorphous and pseudo- amorphous structure according to the order characteristics. Some researchers also divided it to be XRD amorphous and TEM amorphous from the perspective of observation. Furthermore, it can be divided into metal glass, inorganic glass and organic glass based on the composition. There are still tremendous mysteries in amorphous structure[15,16]. Particularly, no convincing conclusion on multiple oxide materials has been achieved yet. Some studies demonstrated that amorphous structure was advantageous in performance mostly because of its structural flexibility[17]. Some others argued that such performance advantage of amorphous struc- ture was contributed by high-concentration lattice defects or large surface area[18]. However, none of these studies discussed the key factor of amorphous structure and the degree of order[19].

To comprehensively understand the effect of amorphous structure of composite oxide, amorphous oxides were analyzed by XRD, HRTEM and EXAFS methods. Traditional structural analysis of the material is mainly based on diffraction phenomenon of long-range order structure and thus it is inapplicable to amorphous structure. By contrast, EXAFS is applicable to both crystal and amorphous structures and is therefore an effective method to explore the local atomic structural information[20]. In addition, as reported, no evident solid solution was generated in the RuO2-ZrO2system[21]. Nevertheless, in our previous thermodynamic study, it was found that the system may gain unstable RuO2-ZrO2with high solid solubility[13]. In other words, thermal decomposition at the critical temperature may retain disordered ions of precursor in composite oxides, resulting in high mutual solubility in the RuO2-ZrO2system. However, such a non-equilibrium phase has not been reported yet. In this paper, the microstructure of non-equilibrium phase was predicted by ab initio calculation based on density functional theory (DFT). The microstructure of RuO2-ZrO2coating that has high specific capacitance was analyzed jointly by XRD, HRTEM and EXAFS, as compared to the DFT prediction. The relationship between the performance and the microstructure of the prepared material will be discussed.

2 EXPERIMENTAL

2. 1 Preparation of the electrode materials

The RuO2-ZrO2coating was prepared by thermal decom- position method at a critical temperature of about 290 ℃[13,14]. In typical, ruthenium trichloride and ZrCl4with a nominal molar ratio of 5:5 were separately dissolved in absolute ethyl alcohol under ultrasonic vibration. These two solutions were then mixed evenly and held statically at room temperature for 12 h. For comparison, Ti/RuO2, Ti/ZrO2and Ti/RuO2-ZrO2coating electrodes were also prepared at the crystalliza- tion temperature of 450 ℃[13,14]. Due to volatilization of the precursor during thermal decomposition, the Ru/Zr atomic ratio in the amorphous RuO2-ZrO2system was quantitatively analyzed by inductively coupled plasma (ICP) measurement by ARCOS SOP (Germany). The electrochemical property of the composite coatings was studied in 0.5 M H2SO4aqueous solution with a CHI660D electrochemical workstation in a conventional three-electrode system equipped with a Pt foil of 2 cm2and a saturated calomel electrode (SCE) as the counter and reference electrodes, respectively. The phase structure of the electrode was analyzed by X-ray diffraction (XRD, Philips. X pert-MPD X) with CuKa radiation.

2. 2 HRTEM characterization

Microstructure of the RuO2-ZrO2coating was observed using Tecnai G2 F20 S-TWIN (200 KV) field emission TEM in both light field image and electron diffraction pattern of the dark field. The in situ phase changes of the composite coating were monitored during an in situ annealing process.

2. 3 EXAFS characterization

The K-bound EXAFS of Zr was collected in the 4W1B beam experimental station of Beijing Synchrontron Radiation Laboratory. Energy of the energy storage ring and the maximum beam intensity were 2.2 GeV and 80 mA, respectively. The monochromator was the double crystals of Si(111) face. The K-bound EXAFS of Ru was collected in the BL14W beam experimental station of Shanghai Synchrontron Radiation Laboratory. Energy of the energy storage ring and the maximum beam intensity were determined to be 2.2 GeV and 80 mA, by using the double crystals of Si(111) face as the monochromator. The spectra were recorded under the room temperature transmission mode. The test results of pure cubic ZrO2and pure square RuO2that had been prepared at 450 ℃ were used as the reference data. The energy calibration was conducted by using the appointed absorption spectral point (17998 eV) of ZrO2powder as the baseline. The EXAFS function k3x(k) was gained after normalization of absorption edge and background reduction. In the equation, energy was converted into the spatial vibration structure from 2 to 15 ?-1. Value of k3x(k) was the weight of k3. The radial structure function of R space was acquired by Fourier transform and then compared with the radial distribution function of standard oxide samples, getting coordination information of Zr and Ru in samples. On this basis, the corresponding coordination structure was fitted by the ARTEMIS software.

Fig. 1. Super cell of (a) rutile structure of RuO2 and (b) fluorite structure of ZrO2

2. 4 Structural calculation

RuO2has a rutile structure and its space group is P42/mnm (Fig. 1a)[22]. Ab initio calculation based on DFT was accomplished by the Vienna ab initio simulation package (VASP) software package. Local Density Approximate (LDA) and General Gradient Approximate (GGA) were applied for exchanging correlation potentials. Both were approximation methods. The wave function of system was extended through the plane wave and the cut-off energy of the plane wave was chose to 520 eV. The structure was calculated by self- consistent wave function. The samples were collected from the Brillouin zone using 2 × 2 × 1 super cells and 6 × 6 × 6 Monkhoot-Pack special points, and the convergence standard was the total energy change of each atom lower than 2 × 10-5eV. To calculate lattice parameters more accurately, structural model of oxide crystal cell was optimized geometrically. The space group of fluorite structure ZrO2is Fm3m (Fig. 1b). The 2 × 1 × 1 super cell Zr8O16was established and four calculation source files (POSCAR, POTCAR, INCAR and KPOINTS) were created under the Linux operating environ- ment. VASP was used for the simulation computation of ab initio to the super cells. According to the principle of total energy minimization, the cell volume was optimized and the optimization energy of cells was calculated simultaneously. In computation, the cut-off energy (Ecut) was set at 520 eV and the Brillouin zone was determined to be the 4 × 4 × 4 Monkhorst-Pack form in order to assure high calculation accuracy during cell optimization. In the optimization process, ISIF = 3, which means that shape and volume changes of the original cells are allowed. Structural and energy calculation were accomplished in the reciprocal space under the periodic boundary condition.

For RuO2-ZrO2, the lattice parameters of rutile and fluorite were calculated under above conditions. To determine cell volume V0, the total cell energy (E) under 0 K was viewed as the function of volume V. Based on the ab initio DFT program, the E-V curve was fitted by the famous Birch-Murnaghan equation (1), getting energy and volume close to equilibrium conditions. Revised and related structure data were acquired:

3 ELECTRODE STRUCTURE AND ITS RELATION TO CAPACITIVE PERFORMANCE

3. 1 EXAFS analysis

EXAFS of local structure is a very useful tool to analyze the local tissue and fine structure. However, an EXAFS analysis on Ru-Zr has not been reported yet. In this paper, local structural information of the RuO2-ZrO2coating was explored by the EXAFS method to disclose the role of Zr in improvement of conductivity and capacitance of oxide coating with Ru. Fourier transform spatial curves of experimental K3and fitted K3of Ru-K edge and Z-K edge of RuO2-ZrO2coating prepared by thermal decomposition at 290 ℃ are shown in Fig. 2a. For the convenience of comparison, the curve of RuO2sample prepared by thermal decomposition at 450 ℃ is also given.

As can be seen, the central atom Ru and the nearest and second nearest atoms are reflected clearly, which are manifested on the first and second shells in the spectral line. They reflect M-O and M-M bonds, respectively. The first center shells of the 290 and 450 ℃ samples at 0.18 nm are similar. Both are formed by Ru-O bonds, indicating that they have oxide structures, as RuO2belongs to tetragonal system and consists of two 0.18 nm long Ru-O bonds. Peak positions and shapes at two preparation temperatures keep consistent basically, reflecting the high peak intensity. Generally, peak intensities of the second shell differ significantly. RuO2coating has perfect Ru-Ru bonding and evident crystalline characteristics, which is proved by the large peak. The peak shape and position are in good accordance with previous researches[23]. The peak of the second shell of the RuO2-ZrO2coating prepared at 290 ℃ is very low, implying the strong instability of Ru-Ru bonding. Particularly, peak positions of two coatings are significantly different, which is caused by their great structural difference. According to preliminary judgment, the dissolving of Zr ions might have generated the displacement of Ru ions.

Fig. 2. Radial distribution function (RDF) curves of RuO2-ZrO2: (a) Ru-K edge, and RuO2 sample prepared at 450 ℃, used as reference; (b) Zr-K edge, and ZrO2 sample prepared at 450 ℃, used as reference

The Fourier transform spatial curves of experimental K3and fitted K3of Zr-K edge of the RuO2-ZrO2coating which was prepared by thermal decomposition at 290 ℃ are shown in Fig. 2b. On the curves, the central atom Zr and the nearest and second nearest atoms are reflected clearly, which are manifested on the first and second shells in the spectral line. They reflect M-O and M-M bonds, respectively. For both samples prepared by decomposition at 290 and 450 ℃ respectively, the first shells of Zr all center at 0.2 nm. In other words, peak position at two preparation temperatures keeps constant and the sharp peaks are alike, showing the high peak intensity. The initial fitting of experimental data by combining the ZrO2crystal structure reveals that this shell is related to O atoms which are the closest to the central atom. The shell mainly reflects Zr-O bond. This indicates that RuO2-ZrO2coatings prepared at 290 and 450 ℃ are oxides.

The second shell peaks of 290 and 450 ℃ samples are different significantly when the center is at 0.2～0.5 nm. The curve of 290 ℃ sample shows obvious amorphous characteristics. The second shell is Zr-Zr peak and the fitted bond length is 0.362 nm, which is equivalent to the previously reported bond length of low-temperature cubic ZrO2[24]. This demonstrates that the 450 ℃ sample is a cubic-phase ZrO2, which is consistent with XRD result (Fig. 3).

Fig. 3. XRD patterns of Ti/RuO2-ZrO2 electrodes prepared at different temperature

The second shell peak of RuO2-ZrO2amorphous coating prepared by thermal decomposition at 290 ℃ is relatively weak, but it still has crystal characteristic spectral line. Therefore, this tissue has an obvious order. It is believed that binary oxide is a disordered amorphous structure, that is, short-range ordering and long-range disordering structure. The second shell has two peaks near 0.31 nm, which are Zr-Ru and Zr-Zr according to fitting. Since Zr-M mixed bonds will be formed by dissolving smaller Ru ions, Zr-Ru and Zr-Zr have far shorter average bond length than the Zr-Zr bond in the 450 ℃ sample (0.362 nm). In a local region, Ru and Zr can be replaced mutually. This fully confirms that the prepared oxide is the amorphous alternative solid solution with short-range ordering and long-range disordering structure. This structure is called the “amorphous solid solution”.

3. 2 In-situ analysis of the solid solution structure

The crystallization process of amorphous structure has been analyzed previously by in situ electron microscope[25]. Since the prepared material is an unstable amorphous solid solution, a more effective in situ analysis is required. The HRTEM images of RuO2-ZrO2coatings are shown in Fig. 4. In Fig. 4a, the RuO2-ZrO2coating presents an amorphous morphology with short-range ordering and long-range disordering structure. Fig. 4b shows that the electron diffraction of this structure is a typical ring pattern, typical for an amorphous structure. However, it can be seen from Fig. 4a and 4d (rectangles) that the whole light field image is dominated by nanoparticles (radius is about 0.29 nm). Buckling and arrangement of distorted lattice points are observed in the enlarged images. Preliminarily, these two types of position ions are viewed in the same region and form the alternative solid solution.

Fig. 4. HRTEM of RuO2-ZrO2 coating prepared at 290 ℃: (a) (b) (c) before and (d) (e) (f) after electron beam annealing

HRTEM images taken on in situ heating were used to analyze the crystallization temperature of the amorphous solid solution. After 15 min of electron beam annealing, the tissues were still in disordered arrangement, belonging to typical amorphous structure. Re-arrangement of the original lattice points was observed. As seen in the representative region in Fig. 4a, the approximate arrangement of 0.29 nm nanopar- ticles was changed to the arrangement of 0.30～0.22 nm nanoparticles in Fig. 4d, implying the occurrence of solid decomposition. Fig. 4b, 4c and Fig. 4e, 4f are the SEAD and FFT images of the samples before and after the electron beam annealing, respectively. Compared to Fig. 4b and 4e, Fig. 4c and 4f show that the original diffusion ring was narrowed slightly and a new ring was developed. From the diffraction ring of SEAD shown in Fig. 4e, the radii of these two regions are calculated to be around 0.30 and 0.22 nm respectively by the above method. This means that one amorphous body and ring have been decomposed into two, respectively. This is consistent with the observation of light field image. According to the in situ HRTEM observation during annealing, the original lattice points were rearranged after the annealing of RuO2-ZrO2and one amorphous body was decomposed into two by RuO2and ZrO2. To sum up, this system would produce Ru-Zr oxide with high solid concentration. The phase change belonged to spinodal decomposition reaction[13].

3. 3 Material calculation and confirmation of solid solution structure

According to preliminary judgments based on the above structural characterization, the Ru-Zr oxide prepared by thermal decomposition at a critical crystallization temperature is a kind of amorphous solid solution with short-range ordering and long-range disordering structure. Under equilibrium state, Ru4+would not produce obvious solid solution in ZrO2[21]. Colomer and Jurado[26]reported that solid solubility of Ru in RuO2-ZrO2solid solution prepared through polymer sol-gel method was 8～10%. Djurado et al[27]found that the solid solubility of RuO2in RuO2-ZrO2prepared by thermal decomposition of nitriate oxide was 10～12.5%. Kimura and Goto[28]prepared RuO2and Y by MOCVD to stabilize ZrO2. The XRD result demonstrated that the dissolved load of RuO2reached about vol. 25%. However, the RuO2-ZrO2prepared by thermal decomposition in this paper has a high solid solubility. Therefore, it is necessary to calculate its structure to determine the phase structure of microcrystal solid solution and cell parameters.

Fig. 5. Structure diagram of the RuO2-ZrO2 solid solution based on (a) RuO2 and (b) ZrO2

The structure of RuO2-ZrO2is shown in Fig. 5. Different positive ions replace with each other, forming an alternative oxide solid solution. The lattice parameters of RuO2-ZrO2were calculated using rutile and fluorite under above conditions. To determine cell volume V0, the total cell energy (E) under 0 K was viewed as the function of volume V. Fluorite and rutile are two possible structures of Ru-Zr composite oxide. Their space lattice groups are Fm3m and P42/mnn, respectively. In fluorite cells, the positive ions are in the center of cube formed by 8 O atoms. In the rutile structure, the positive ions are in the center of deformed octahedron formed by 6 O atoms, including two short O-O bonds and four long O-O bonds[28]. The O-O bond length is an important structural factor that influences hardness of these two structures. The O-O bond length (2.532 ?) of fluorite ZrO2under 0 K and 0 GPa and the shortest O-O bond length of rutile ZrO2(2.966 ?) (Fig. 6a) were calculated by structural optimization based on ab initio. The O-O bond lengths of fluorite and rutile RuO2were calculated to be 2.380 and 2.415 ?, respectively (Fig. 6b). Haines[29]also compared them and found that the shortest O-O bond lengths of fluorite and rutile structures were 2.429 and 2.468 ?, which had about 2.0% (fluorite) and 2.2% (rutile) difference as compared to the above results.

The calculated data of cell oxide and fine structural analysis data are listed in Table 1. They were used to investigate the reliability of calculated results. According to the Zr-K edge of fluorite structure calculated by EXAFS method, the Zr-O bond length of the first shell was 2.131 ± 0.004 ? and the coordination number was 4.1, while those of the second shell were 2.208 ± 0.005 and 3.6 ?, respectively. The average bond length was 2.167 ? and the total coordination number was 7.7. According to the ab initio calculation results, the bond length of Zr-O was 2.167 ? and the coordination number was 8. Therefore, the EXAFS method and the ab initio were basically equivalent in terms of the average bond length and total coordination number. Nevertheless, they produced significantly different cell parameters of the rutile structure. Firstly, the coordination number of the first shell of Zr-O calculated by EXAFS was 5.2, while that by ab initio calculation was 2. Moreover, there was a great gap between two methods with respect to the coordination numbers of the second shell. Based on the above comparison, the RuO2-ZrO2solid solution may be closer to the fluorite structure. Same conclusions could be drawn by comparing structural data of Zr-Ru and Zr-Zr bonds. In other words, structural data of EXAFS and ab initio of fluorite structure are closer.

Fig. 6. (a) Rutile and (b) fluorite structures of ZrO2

3. 4 Discussion on high activity of solid solution structure

The structural analysis confirmed that the prepared RuO2-ZrO2is a type of oxide solid solution with microcrystal arrangement. As a result, the prepared RuO2-ZrO2electrodes have high specific capacitance.

Firstly, different radii and electronic structures of Ru and Zr atoms will cause lattice distortion of solid solution and change the electronic shell structure due to their interaction, thus increasing the active lattice number. These changes will increase electrocatalytic activity of oxides and further bring high “active site density” of oxides. According to Trasatti’s opinion[30], active sites of electrode are closely related to electrode structure. Crystal and structural defects are active sites of electrodes. The content of inert ZrO2decreases once Ru and Zr form the solid solution. The active lattice number of Ru-containing oxide is doubled and the active site density is increased significantly after mutual solid solution. Electron factors change because of lattice distortion, which can further increase the active site density of oxides.

Table 1. Comparison between the Fitted EXAFS Data of RuO2-ZrO2 with ab initio Calculation Results

Secondly, RuO2-ZrO2is a solid solution with microcrystal disordered arrangement and has very high electrochemical roughness Rf. Study on electrochemical roughness of RuO2-ZrO2electrodes showed that the RuO2-ZrO2electrodes prepared at 290 ℃ have the highest electrochemical roughness. This is mainly caused by small diameter of the original microcrystal (about 0.8 nm). Small granularity not only contributes short diffusion distance and easy protolysis in RuO2-ZrO2, but can also increase the specific surface area of electrodes and the number of electric active sites[31-33]. Therefore, the smaller the oxide particles are, the higher the active surface will be.

Fig. 7. Effect of preparation temperature on (a) number of active sites and (b) surface roughness of RuO2-ZrO2 electrodes

Finally, the microcrystal disordered structure of RuO2-ZrO2is beneficial to increase proton diffusion of coating and the existence of microcrystal leads to high conductivity of electrodes, thus failing to achieve equilibrium between electron and proton conductivity. Therefore, active sites on the coating surface and inside could be fully used.

Calculations of active site and electrochemical roughness are introduced in the reference[34]. The electrochemical active sites and electrochemical roughness data of RuO2-ZrO2electrodes prepared under 280～450 ℃ are given in Fig. 7. The RuO2-ZrO2electrode prepared at 290 ℃ achieves the highest electrochemical active sites and roughness.

Based on above analysis, the RuO2-ZrO2electrode has high electrochemical roughness (Rf) and thereby can get high “active surface”. Besides, the interaction of different positive ions in solid solution, or the synergistic catalysis, increases active site density of electrode materials (nsites) significantly. It is the superposition of “active surface” and “synergistic catalysis” that contributes to the unusual high specific capacitance of RuO2-ZrO2electrodes.

To analyze whether the RuO2-ZrO2solid solution involves such superposition, the specific capacitances of several groups of RuO2-ZrO2and RuO2prepared under different decomposi- tion temperature are compared in Fig. 8. The action time of the amorphous structure, the second component (element) and the “synergistic catalysis” of interaction of different positive ions could be known.

Firstly, amorphous RuO2and nano RuO2are compared. Without “synergistic catalysis” of other positive ions and influence of the second component, the specific capacitance is increased by 4.02 times when RuO2transits from crystalline structure to the amorphous structure. This indicates that the action time of amorphous structure is generally about 4 times higher than that of crystalline structure.

Secondly, adding the second component increases the specific capacitance by 2.96 times compared to those of crystal RuO2-ZrO2and RuO2. This indicates that the action time of composition is generally about 3.

If no “synergistic catalysis” occurs, the specific capacitance (Cs) of amorphous RuO2-ZrO2can be calculated according to the following equation (2):

In fact, the specific capacitance of amorphous RuO2-ZrO2solid solution prepared at critical crystallization temperature reached 949 F·g-1. The additional specific capacitance growth of 204.1 F·g-1shall be attributed to “synergistic catalysis” of different positive ions. In other words, the “synergistic catalysis” increases the specific capacitance of RuO2-ZrO2electrodes by 27.5%.

Fig. 8. Comparison of specific capacitances of several electrodes prepared by thermal decomposition method at different temperature. The Cs was obtained using galvanostatic charge-discharge test at 5 mA·cm-2

Substantially, adding the second component of the Ru-containing binary oxide is expected to increase the electrocatalytic activity, and specific surface area of RuO2. It is easy to understand that the synergistic effect between two oxides is needed in order to increase activity of RuO2. Two oxides should be closely related and form a composite or solid solution for interaction of different positive ions, so “synergistic catalysis” could be used completely. It is difficult to acquire synergistic effect when two oxides are simply mixed. The amorphous structure is divided into topology disorder arrangement and microcrystal disorder arrangement. If the Ru-containing binary oxide belongs to the topology disorder arrangement, the binary oxide is the mixture of two oxides. The second component can be served as a carrier and increase dispersibility and specific capacitance of RuO2. These are the consequences of increased utilization of RuO2. This means that the second component will not influence the essential activity of RuO2and cause “synergistic effect”. The amorphous RuO2-ZrO2solid solution prepared at 290 ℃ makes full use of high activity and high “external active surface” of amorphous material as well as the “synergistic catalysis” of positive ions brought by the solid solution. High specific capacitance of amorphous RuO2-ZrO2solid solution is the results of superposition of multiple advantages. The intrinsic specific capacitance under low circulation speed reaches 1 319.5 F·g-1, which is close to the theoretical specific capacitance of RuO2.

Further researches on why amorphous structure has higher specific capacitance than existing hydration Ru-containing oxides are needed. Based on previous comparative analyses, short-range ordered microcrystal structure is an important reason because the occurrence of tremendous microcrystal increases the density of high electric conductors significantly. Adding Zr4+expands nanoparticles and is conducive to the diffusion of ions from electric catalytic reaction and reducing resistance of the electric channel, thus increasing the redox ability of materials significantly[35]. However, how to use this active substance with high intrinsic specific capacitance effectively in practical electrode materials is another topic that shall be explored urgently.

4 CONCLUSION

The microstructure of RuO2-ZrO2with high specific capacitance was analyzed by XRD, HRTEM and EXAFS in this paper. It concludes preliminarily that the prepared RuO2-ZrO2is identified as a kind of quasi-amorphous solid solution phase. This solution phase is further explored by in-situ annealing based on HRTEM. Combining with ab initio calculation, the prepared RuO2-ZrO2is determined to be a type of quasi-amorphous solid solution that has similar structure with fluorite. This quasi-amorphous structure with high solid solubility can explain the high specific capacitance of Ru-Zr oxide. The quasi-amorphous solid solution structure is conducive to “synergistic catalysis” induced by the interaction of positive ions. RuO2-ZrO2coating can gain high “active site density” and “active surface”, thus developing high specific capacitance.

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