LIU Xiaochun, LING Xiaoxiao & JAHN Bor-ming
1 Institute of Geomechanics, Chinese Academy of Geological Sciences, Beijing 100081, China;
2 Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;
3 Department of Geological Sciences, National Taiwan University, Taipei 10699, China
Abstract The Grove Mountains, 400 km south of the Chinese Antarctic Zhongshan Station, are an inland continuation of the Pan-African-aged (i.e., Late Neoproterozoic/Cambrian) Prydz Belt, East Antarctica. In this paper we carried out a combined U-Th-Pb monazite and Sm-Nd mineral-whole-rock dating on para-and orthogneisses from bedrock in the Grove Mountains.U-Th-Pb monazite dating of a cordierite-bearing pelitic paragneiss yields ages of 523 ± 4 Ma for the cores and 508 ± 6 Ma for the rims. Sm-Nd mineral-whole-rock isotopic analyses yield isochron ages of 536 ± 3 Ma for a coarse-grained felsic orthogneiss and 507 ± 30 Ma for a fine-grained quartzofeldspathic paragneiss. Combined with previously published age data in the Grove Mountains and adjacent areas, the older age of ~530 Ma is interpreted as the time of regional medium- to low-pressure granulite-facies metamorphism, and the younger age of ~510 Ma as the cooling age of the granulite terrane. The absence of evidence for a Grenville-aged (i.e., Late Mesoproterozoic/Early Neoproterozoic) metamorphic event indicates that the Grove Mountains have experienced only a single metamorphic cycle, i.e., Pan-African-aged, which distinguishes them from other polymetamorphic terranes in the Prydz Belt. This will provide important constraints on the controversial nature of the Prydz Belt.
Keywords U-Th-Pb monazite dating, Sm-Nd mineral-whole-rock dating, Pan-African-aged, Grove Mountains,East Antarctica
Discovery of the Pan-African-aged (i.e., Late Neoproterozoic/Cambrian, ~550–500 Ma) high-grade tectonothermal event in Prydz Bay, East Antarctica (Fitzsimons et al., 1997;Carson et al., 1996; Hensen and Zhou, 1995; Zhao et al.,1995, 1992) constituted one of the most important steps in understanding Antarctic geology and led to recognizing a new orogen, termed the Prydz Belt (Zhao et al., 2003;Fitzsimons, 2000) or Kuunga Orogen (Boger, 2011), in the interior of what had been considered a single continent, East Gondwana. However, since the Pan-African-aged event in the Prydz Belt overprinted not only the Grenville-aged (i.e.,Late Mesoproterozoic/Early Neoproterozoic, ~1000–900 Ma) Rayner Complex, but also Archean-Paleoproterozoic cratonic blocks, there has been an extended debate on the extent, process and role of both Grenville-aged and Pan-African-aged tectonothermal events, which has resulted in several models for reassembling Rodinia and Gondwana(Fitzsimons, 2003; Harley, 2003; Yoshida et al., 2003; Zhao et al., 2003).
The Grove Mountains, situated about 400 km south of Prydz Bay (Figure 1a), are considered as an inland continuation of the Prydz Belt (Liu et al., 2003a, 2002; Zhao et al., 2003, 2000; Mikhalsky et al., 2001b). U-Pb zircon analyses for bedrock from the Grove Mountains revealed an Early Neoproterozoic mafic and felsic igneous intrusion and a Pan-African-aged granulite-facies metamorphism and widespread charnockitic and granitic magmatism (Liu et al.,2007a, 2006; Zhao et al., 2003). Zircons from glacial moraines collected from the Grove Mountains also only record a Pan-African-aged metamorphic event (Hu et al.,2016; Wang et al., 2016a, 2016b; Liu et al., 2009a). In order to further examine the question on whether the Grove Mountains have experienced only a single Pan-African-aged metamorphic cycle, or represent a polymetamorphic terrane as other parts of the Prydz Belt, we carried out a combined U-Th-Pb monazite and Sm-Nd mineral-whole-rock dating on para- and orthogneisses from bedrock. The results support the suggestion that the Grove Mountains are a Pan-African-aged monometamorphic terrane in the Prydz Belt (Liu et al.,2013).
Figure 1 a, Geological sketch map of the Prince Charles Mountains-Prydz Bay region with inset showing its location in East Antarctica(modified after Fitzsimons (2003), Mikhalsky et al. (2001a)). b, Geological map of the Grove Mountains showed on a remote sensing image (modified after Liu et al. (2009a)).
The Grove Mountains are made up of 64 nunataks of different sizes, which are spread over an area of approximately 3200 km2. The bedrock in this area consists mainly of high-grade metamorphic rocks and abundant intrusive charnockites and granites (Figure 1b). The metamorphic rocks are dominated by felsic orthogneisses and mafic granulites, with minor quartzofeldspathic and pelitic paragneisses and calc-silicate rocks (Liu et al., 2003b, 2002). Peak P-T conditions of high-grade rocks are estimated at 6.1–6.7 kbar and 850oC (Liu et al., 2003b), which are very similar to those obtained for rocks from Prydz Bay. The protoliths of felsic orthogneisses and mafic granulites were emplaced at ~920–910 Ma, and then experienced metamorphism at ~550–535 Ma (Liu et al., 2007a; Zhao et al., 2003). In addition, detrital zircons from a paragneiss record a magmatic age of~2080 Ma and a metamorphic age of ~2050 Ma (Liu et al., 2007a). Charnockites and granites were emplaced at 547–501 Ma (Liu et al., 2006; Zhao et al.,2000).
Lateral moraines occur widely on glaciers in the Grove Mountains and are particularly concentrated in the area near the Mason Peaks, Wilson Ridge, Mount Harding and Gale Escarpment. A number of medium-pressure paragneisses and high-pressure pelitic and mafic granulites, which are distinct from the bedrock, were identified from the glacial moraines and were inferred to have originated from the Grove Subglacial Highlands with an area of about 200 ×300 km2(Chen et al., 2018; Wang et al., 2016a, 2016b; Liu et al., 2009a). The deposition ages of paragneiss precursors were inferred to be younger than ~1090–940 Ma (Wang et al., 2016a), and high-pressure metamorphism was dated at~560–540 Ma (Chen et al., 2018; Wang et al., 2016b; Liu et al., 2009a). The P-T path calculated for high-pressure granulites involved peak metamorphic conditions of 11.6–14.0 kbar and 770–840°C, and a subsequent near-isothermal decompression of 6 kbar (Chen et al., 2018;Liu et al., 2009a). These data provide evidence for a collisional tectonic setting for the Pan-African-aged event in the Grove Subglacial Highlands.
Figure 2 Photograph, photomicrographs and BSE images showing the field relationships and mineral assemblages of para- and orthogneisses from the Grove Mountains. a, Field relationships of felsic orthogneiss, mafic granulite and pelitic and quartzofeldspathic paragneiss from Bryse Peaks. b, Photomicrograph (plane-polarized light) of the mineral assemblage of inequigranular garnet + biotite +cordierite + plagioclase + spinel in pelitic paragneiss sample BP2-3 from Bryse Peaks. c, BSE image of monazite occurring as an intergranular phase among biotite, cordierite and plagioclase in sample BP2-3. d, BSE image of monazite occurring as an inclusion in garnet in sample BP2-3. e, Photomicrograph (plane-polarized light) of the mineral assemblage of coarse-grained garnet + perthite + quartz with a small chlorite flake in felsic orthogneiss sample WR1-2 from Wilson Ridge. f, Photomicrograph (plane-polarized light) of the mineral assemblage of fine-grained garnet + orthopyroxene + biotite + perthite + quartz in quartzofeldspathic paragneiss sample WR1-4 from the Wilson Ridge. Mineral abbreviations: Bt–biotite, Chl–chlorite, Crd–cordierite, Grt–garnet, Mnz–monazite, Opx–orthopyroxene,Pl–plagioclase, Pth–perthite, Qtz–quartz, Spl–spinel, Zrn–zircon.
Three garnet-bearing gneisses from the northern Grove Mountains were selected for a geochronological study.Sample BP2-3 is a typical pelitic paragneiss collected from Bryse Peaks. The paragneiss, together with quartzofeldspathic paragneiss and banded mafic granulite, constitutes a strongly foliated layer of 50 m thick sandwiched between layers of felsic orthogneiss (Figure 2a). It has mineral assemblage of garnet (7%) + biotite (30%) + cordierite(20%) + plagioclase (40%) + spinel (3%) (Figure 2b), with minor ilmenite, zircon and monazite. An Al2SiO5phase(sillimanite?) was identified as tiny inclusion in cordierite using backscattered electron (BSE) imaging. The grain size of garnet porphyroblasts ranges from 1 to 3 mm, but other minerals are mostly <1 mm. Monazite commonly occurs as an intergranular phase (Figure 2c), or as inclusions in garnet(Figure 2d), biotite, cordierite and plagioclase. It appears in textural equilibrium with major minerals in the rock.
Sample WR1-2 was taken from a garnet-rich domain of the felsic orthogneisses from Wilson Ridge. The rock is relatively coarse-grained and consists of garnet (8%), biotite(2%), plagioclase (10%), perthite (45%) and quartz (35%)(Figure 2e). Garnet is subhedral or anhedral, with grain sizes of 2–5 mm. It commonly contains inclusions of quartz.The felsic orthogneiss generally experienced low-grade alteration. Biotite was partially or entirely replaced by chlorite. Randomly oriented muscovite has grown in small amount along the margins of some perthite and plagioclase grains.
Sample WR1-4 is a fine-grained quartzofeldspathic paragneiss collected also from Wilson Ridge. This paragneiss occurs as layers of 5–200 cm wide in felsic orthogneiss, and was commonly intruded by thin pegmatite veins, which are parallel to the regional gneissosity of the paragneiss. The rock shows near-equigranular textures,composed of garnet (1%), orthopyroxene (8%), biotite(25%), plagioclase (5%), perthite (45%), quartz (15%) and ilmenite (1%) (Figure 2f). Garnet is anhedral, with grain sizes ranging from 0.2 to 1 mm. Orthopyroxene is subhedral and, in some cases, is concentrated in some domains.
U-Th-Pb monazite analyses were conducted using a Cameca IMS–1280 large-radius SIMS at the Institute of Geology and Geophysics, Chinese Academy of Sciences,Beijing. Prior to analysis, monazite was extracted using conventional techniques, including crushing, sieving, heavy liquid separation and handpicking. The resulting monazite grains were then mounted in epoxy discs along with a standard monazite RW-1 (Ling et al., 2016) and polished to expose the grain centers. Internal structures of monazite were revealed by BSE imaging. For the SIMS analyses, the instrument descriptions and analytical procedures are the same as those described by Li et al. (2013). The primary O2–ion beam spot is about 20 μm in size. Positive secondary ions were extracted with a 10 kV potential. In the secondary ion beam optics, a 60 eV energy window was used, together with a mass resolution of ~5400 (at 10%peak height) to separate Pb+peaks from isobaric interferences. A single electron multiplier was used in ion-counting mode to measure secondary ion beam intensities by peak jumping mode. Each measurement consists of 7 cycles. Pb/U ratio, U and Th concentrations were calibrated against monazite RW-1 [Pb/U age=904.15 ±0.26 Ma, Th=11.8 ± 0.5% (1σ), Th/U=42.5 ± 1.5 (1σ)]. A long-term uncertainty of 1.5% (1 RSD) for206Pb/238U measurements of the standard monazite was propagated to the unknowns (Li et al., 2010). Common Pb was corrected using the207Pb-based method (Li et al., 2013; Williams,1998), with the terrestrial lead isotope composition at corresponding ages (Stacey and Kramers, 1975). Ages were calculated with the ISOPLOT software (Ludwig, 2001).
Trace element analyses of monazite were carried out using laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) at the Wuhan Sample Solution Analytical Technology Co., Ltd., Wuhan, China. Detailed operating conditions for the laser ablation system and the ICP–MS instrument and data reduction are the same as described by Zong et al. (2017). Laser sampling was performed using a GeolasPro laser ablation system that consists of a COMPexPro 102 ArF excimer laser(wavelength of 193 nm and maximum energy of 200 mJ) and a MicroLas optical system. An Agilent 7700e ICP–MS instrument was used to acquire ion-signal intensities. Helium was applied as a carrier gas. Argon was used as the make-up gas and mixed with the carrier gas via a T-connector before entering the ICP. A “wire” signal smoothing device is included in this laser ablation system (Hu et al., 2015). The spot size and frequency of the laser were set to 24 μm and 5 Hz, respectively. Trace element compositions of monazite were calibrated against various reference materials(BHVO-2G, BCR-2G and BIR-1G) without using an internal standard (Liu et al., 2008). Each analysis incorporated a background acquisition of approximately 20–30 s followed by 50 s of data acquisition from the sample. An Excel-based software ICPMSDataCal was used to perform off-line selection and integration of background and analyzed signals,time-drift correction and quantitative calibration for trace element analyses (Liu et al., 2008).
Sm-Nd mineral-whole-rock isotopic analyses were performed using a 7-collector Finnigan MAT–262 mass spectrometer at the Université de Rennes 1, France. The analytical procedures are similar to those reported by Jahn et al.(1996). Sm-Nd isochron ages were calculated using the program ISOPLOT 2.06 of Ludwig (1999). Input errors (2σ)used in age calculations are147Sm/144Nd=0.2% and143Nd/144Nd=0.005%. The quoted errors in isochron ages represent two standard deviations (2σ). Sm-Nd model ages(TDM) were calculated in two ways. The one-stage depleted mantle model age (TDM1) is calculated assuming a linear isotopic evolution of the depleted mantle reservoir from εNd(T)=0 at 4.56 Ga to +10 at the present. The two-stage model age (TDM2) is obtained assuming that the protolith of the granitic magmas has a Sm/Nd ratio of the average continental crust (Keto and Jacobsen, 1987). Nd isotopic normalization parameters (147Sm/144Nd=0.2137,143Nd/144Nd=0.51315) used for the calculation of model ages are the same as Liu et al.(2006).
Monazites from pelitic paragneiss sample BP2-3 are ovoid or irregular in shape, with grain sizes ranging from 30 to 200 μm. Most monazite grains show a relatively dark core and a bright rim in BSE images (Figure 3), but some small ones are homogeneous. Eighteen SIMS spot analyses were performed on 12 monazite cores and 6 rims (Table 1). Th and U concentrations are quite variable and indistinguishable between cores and rims, with Th=2.6%–16.1%,U=0.42%–1.80%, and Th/U ratios=2.8–28.4. However, the cores yield relatively old206Pb/238U ages ranging from 539.3 ± 8.2 to 509.5 ± 7.5 Ma, whereas the rims produce younger ages from 518.1 ± 7.6 to 498.6 ± 7.3 Ma. All these data points give a weighted mean206Pb/238U age of 518 ±5 Ma (MSWD=1.7) (Figure 4), which is in good agreement with the weighted mean208Pb/232Th age of 518 ± 3 Ma(MSWD=1.3; excluding spot 14 with an older age of 551.7± 5.9 Ma). If calculated separately, 12 core and 6 rim analyses yield weighted mean206Pb/238U ages of 523 ±4 Ma (MSWD=0.92) and 508 ± 6 Ma (MSWD=0.85),respectively.
Figure 3 Representative BSE images of monazites from pelitic paragneiss sample BP2-3. All monazites showing a relatively dark core and a bright rim. Circles with numbers are SIMS analytical spots with their identification numbers. Ages are given with errors of 1σ. Scale bars are 50 μm.
Eighteen LA–ICP–MS trace element analyses were also undertaken on all dated monazite domains (Table 2).As is the case with Th and U concentrations, trace element concentrations show wide variation that appears unrelated to the zoning visible in the BSE images. Dark cores show Y abundances of 0.73%–3.74% and total rare earth element(REE) contents of 49.95%–58.35%. The chondritenormalized REE patterns are enriched in light REE(LaN/YbN=54–801) and have variable negative Eu anomalies (Eu/Eu*=0.03–0.32) (Figure 5). By contrast,bright rims have Y abundances of 0.85%–3.69% and total REE contents of 51.30%–55.31%. They also display highly fractionated REE patterns (LaN/YbN=55–715) and markedly negative Eu anomalies (Eu/Eu*=0.03–0.08).
Table 1 SIMS U-Pb analyses of monazites from sample BP2-3
Figure 4 Distribution plots of 206Pb/238U ages of monazites from pelitic paragneiss sample BP2-3.
Coarse-grained garnet, plagioclase and perthite from felsic orthogneiss sample WR1-2 and fine-grained garnet,orthopyroxene, biotite, plagioclase and perthite from quartzofeldspathic paragneiss sample WR1-4 were separated for Sm-Nd isotopic analyses together with whole-rock powder (Table 3). The obtained mineral-wholerock isochron ages are 536 ± 3 Ma (MSWD=0.67) for sample WR1-2 (Figure 6), and 507 ± 30 Ma (MSWD=4.6)for sample WR1-4 (Figure 7). The initial143Nd/144Nd ratios(INd) are 0.511450 ± 0.000015 and 0.51130 ± 0.00005,respectively. In addition, the whole-rock analyses yield an initial εNdvalue [εNd(T)] of –9.9 and a two-stage Nd model age (TDM2) of 2.11 Ga for sample WR1-2, and εNd(T)of –13.3 and TDM2of 2.38 Ga for sample WR1-4.
Table 2 Trace element analyses (in ppm) of monazites from sample BP2-3
Since the Pb closure temperature of monazite could exceed 900oC (Cherniak et al., 2004), this accessory mineral was frequently used to date medium- to high-grade metamorphism. Unfortunately, because the internal zoning,as shown in BSE images, of monazites from sample BP2-3 does not match the variation of trace elements (particularly Y contents), the growth relationship between monazite and garnet was not established in this study. The U-Pb age of 523 ± 4 Ma obtained for monazite cores is roughly in accord with the ages (~535–525 Ma) of regional medium-pressure granulite-facies metamorphism in the eastern Amery Ice Shelf–Prydz Bay region (Liu et al.,2009b, 2007b; Kelsey et al., 2007; Ziemann et al., 2005;Fitzsimons et al., 1997; Zhang et al., 1996) and retrograde metamorphic age (~530 Ma) of high-pressure mafic granulites from the Grove Mountains (Liu et al., 2009a).Coupled with the coexistence of monazite and cordierite in the sample, this age is taken to represent the approximate time of medium- to low-pressure granulite-facies metamorphism in the Grove Mountains. Based on geochemical data of zircon and associated minerals in high-grade rocks from the Rauer Group, the zircon rim age of ~510 Ma was interpreted as the time of post-peak fluid infiltration (Harley and Kelly, 2007).The age of 508 ± 6 Ma obtained for monazite rims could also be attributed to post-peak infiltration, since hydrothermal alteration under greenschist-facies conditions has been recognized in sample WR1-2 and some other rocks from the Grove Mountains (Liu et al., 2009a).
Figure 5 Chondrite-normalized REE patterns of monazites from pelitic paragneiss sample BP2-3. Chondrite-normalization values are from Sun and McDonough (1989).
The Nd closure temperature of garnet is generally inferred to be ~700–750oC (Ganguly et al., 1998), although there is a difference between fast and slowly cooled terranes.Therefore, garnet-based Sm-Nd isochron age commonly reflect the time of cooling of garnet through its closuretemperature. The age of 536 ± 3 Ma obtained for coarsegrained sample WR1-2 is similar to the Sm-Nd garnet–whole-rock ages of 538–522 Ma obtained for high-pressure mafic granulites from the Grove Mountains (Liu et al.,2009a). Considering the relatively weak effect of Nd diffusion for large garnet grains, we infer this age quite close to the age of regional metamorphism in the Grove Mountains. In contrast, the age of 507 ± 30 Ma obtained for fine-grained sample WR1-4 is obviously young and has a large uncertainty, indicating a strong Nd diffusion of garnet.Therefore, this age is interpreted as the cooling age of the rock. In fact, this age is also comparable to the monazite rim age mentioned above, and U-Pb ages (~510 Ma) of rutile and titanite and40Ar/39Ar ages (~510–490 Ma) of hornblende and biotite from rocks in the Grove Mountains(Mikhalsky et al., 2001b; Hu et al., unpublished data).Similar Sm-Nd ages (~515–490 Ma) were widely reported in the eastern Amery Ice Shelf–Prydz Bay region (Liu et al.,2007b; Hensen and Zhou, 1995).
Table 3 Sm-Nd isotopic compositions of samples WR1-2 and WR1-4
Figure 6 Sm-Nd mineral-whole-rock isochron diagram for felsic orthogneiss sample WR1-2.
Figure 7 Sm-Nd mineral-whole-rock isochron diagram for quartzofeldspathic paragneiss sample WR1-4.
The Prydz Belt has long been thought to be a typical polymetamorphic belt that underwent both Grenville-aged and Pan-African-aged high-grade metamorphism (Dirks and Wilson, 1995). The earliest geochronological evidence for the Grenville-aged metamorphism in the Prydz Belt comes from garnet-bearing mafic granulites from the S?strene Island. Hensen and Zhou (1995) obtained five Sm-Nd garnet–whole-rock isochron ages for these rocks, and the oldest one of 988 ± 12 Ma was interpreted as the age of the metamorphic event. Subsequently, U-Pb or (U + Th)-Pb monazite ages of ~1030–820 Ma were reported from some metapelites from the Rauer Group and Bolingen Islands(Kelsey et al., 2007; Kinny 1998). Moreover, further detailed SHRIMP U-Pb zircon dating for felsic orthogneisses and mafic granulites from the eastern Amery Ice Shelf–Prydz Bay region demonstrated a widespread existence of this event in the basement of the Prydz Belt(Liu et al., 2014, 2009b, 2007b; Grew et al., 2012; Wang et al., 2008; Carson et al., 2007).
As mentioned previously, the Grove Mountains are an inland continuation of the Prydz Belt. However, the Grenville-aged metamorphic event was not identified from both bedrock and glacial moraines using U-Pb zircon geochronology (Chen et al., 2018; Hu et al., 2016; Wang et al., 2016a, 2016b; Liu et al., 2009a, 2007a). The present U-Th-Pb monazite and Sm-Nd mineral-whole-rock dating for para- and orthogneisses from bedrock have also not manifested the existence of this earlier event. More importantly, the Pan-African-aged metamorphic zircon rims grew directly on magmatic zircon cores of ~920–910 Ma in felsic orthogneisses and mafic granulites, and the Paleoproterozoic detrital zircons from pelitic paragneiss sample BP2-3 uniquely record an imprecise U-Pb lower intercept age of ~500 Ma (Liu et al., 2007a). All these data taken together suggest that the Grove Mountains, while a part of the Prydz Belt, were affected by a single Pan-African-aged metamorphic event. Taking into account the absence of the Grenville-aged metamorphic event in the Archean Rauer Group (Hokada et al., 2016; Kelsey et al.,2007, 2003), it can be concluded that some terranes in the Prydz Belt were not involved in the Grenville-aged orogeny.
A Pan-African-aged monometamorphic terrane in the Grove Mountains provides much better constraints on the nature of the Prydz Belt. The available petrological and geochronological data obtained for bedrock and glacial moraines from the Grove Mountains indicate a Pan-African-aged tectonometamorphic evolution as follows. (1) The crustal rocks were buried to depths of ~40–50 km and underwent high-pressure granulite-facies metamorphism accompanied by charnockitic intrusion at ~560–540 Ma. (2)The high-pressure rocks were exhumed to mid-upper crustal levels and suffered regional medium- to low-pressure granulite-facies metamorphism with concomitant charnockitic and granitic intrusion at ~530 Ma. (3) Crustal extension and greenschist-facies metamorphic overprinting,in association with the widespread emplacement of granites and granitic dykes, took place at ~510–490 Ma. This may reflect a complete orogenic process from continental collision to extensional collapse.
AcknowledgmentsWe would like to thank Liu Xiaohan, Li Jinyan and Huo Dongmin for assistance during field work. The field work was carried out during the 15th Chinese National Antarctic Research Expedition during 1998–1999. We gratefully acknowledge logistic support from the Chinese Arctic and Antarctic Administration and financial support from the National Natural Science Foundation of China (Grant no. 41530209) and the Central Public-Interest Scientific Institution Basal Research Fund(Grant no. JYYWF201819). Critical reviews by E. S. Grew and E. V.Mikhalsky substantially improved the manuscript.
Advances in Polar Science2018年2期