Gan Congjun, Jiang Xuewei, Dong Jie, Zhao Xin, Zhang Qinghua

(State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620)

Synthesis of sulfone-containing polyimide and preparation of hollow fiber membranes

Gan Congjun, Jiang Xuewei, Dong Jie, Zhao Xin, Zhang Qinghua*

(State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620)

A 4,4′-(hexafluoroisopropylidene)diphthalic anhydride- bis[4-(4-aminophenoxy)phenyl] sulfone (6FDA-BAPS) polyamic acid (PAA) was synthesized by using 6FDA and BAPS as reactive monomers andN-methyl-2-pyrrolidone(NMP)asasolvent.ThePAAsolutionwaspreparedintomembranesbycastingtechnologyandwasalsopreparedintoPAAhollowfibermembranesbydrywetspinningprocess.ThePAAmembranesandPAAhollowfibermembraneswereexposedtothehigh-temperaturethermalcyclizationatabout300 ℃toproducea6FDA-BAPSpolyimide(PI)membranesandhollowfibermembranes.Thestructureandpropertiesof6FDA-BAPSPIproductswerestudied.Theresultsshowedthattheobtained6FDA-BAPSPIwasthetargetproductwhichwasoffairlygoodsolubilityinNMP,dimethylacetamideandtetrahydrofuran;the6FDA-BAPSPIpossessedthedenseouterlayerandthelooseandporoussupportlayer;thehollowfibermembraneshadthe5%weightlosstemperatureof511 ℃andbreakingstrength26.5MPa,indicatingrelativelyhighthermalandmechanicalproperties.

polyamic acid; polyimide; hollow fiber membrane; structure; properties

Polyimide (PI) is one of a high performance polymers, exhibiting outstanding properties such as electric insulation, radiation resistance, thermostability and good permeability, and the polymer has been extensively used in micro-electronics, aerospace, high temperature filtration, membrane separation and other fields[1-5].The PI hollow fiber membranes possess enormous utilization potentiality in gas absorption, membrane distillation and membrane bioreactor due to their high thermostability and large specific surface area[6-7].

Here we presents a new polymer containing bulky trifluoromethyl moieties (—C(CF3)2—) in dianhydride and polar group —O— and —SO2— in diamine to weaken the packing density of the molecular chain, and reduce the intermolecular forces as well as the solubility. Meanwhile, the introduction of the trifluoromethyl moieties can increase the free volume of the polymer and accelerate the gases diffusion within the membrane. The polar group —O— and —SO2— in diamine can increase the solubility coefficient of the CO2and H2S. This new PI is expected to improve permeance and separation performance of the PI hollow fiber membranes and has broad application prospects in the field of gas separation membrane.

1 Experimental

1.1 Materials and Measurements

4,4′-(hexafluoroisopropylidene) diphthalicanhydride (6FDA): purity 99%, purchased from Sunlight Pharmaceutical Co., Ltd..Bis[4-(4-aminophenoxy) pheny-l] sulfone (BAPS):purity 98%, purchased from J&K Chemical Ltd.N-methyl-2-pyrrolidone(NMP)andtetrahydrofuran(THF):analyticalpurity,purchasedfromSinopharmChemicalReagentCo..Nicolet8700spectrometer:ThermoElectronCo.,USA.BrukerAvance400nuclearmagnetcresonancespectrometer:BrukerCo.,Switzerland.DiscoveryTGAQ5000IRthermalanalyzer:TAInstrumentCo.,USA.HitachiSU8010scanningelectronmicroscope:HitachiLtd.,Japan.Instron5380tensilestrengthtester:InstronCo.,USA.

1.2 Experimantal method

1.2.1 Preparation of 6FDA-BAPS PI

To synthesize 6FDA-BAPS PI, BAPS (13.040 g) was dissolved in a 250 mL three-neck round-bottomed flask filled with NMP (40 mL) and THF (30 mL). After stirring for 20 min under nitrogen atmosphere, 6FDA (13.394 g) and NMP (80 mL) were slowly added into the solution in twice. The viscosity of the solution increased apparently after stirring 8 h in an ice bath of 3.5 ℃. After 5 h, a colourless sulfone-con-taining poly(amic acid) (PAA) yielded. The intermediate PAA solution was degassed at room temperature, cast onto a glass plate or spin by dry-jet-wet spinning to prepare film or hollow fiber, and then thermally treated to complete the thermal ring-closure reaction up to 300 ℃ in an oven.

1.2.2 Preparation of 6FDA-BAPS PI membranes

PAA membranes were produced by casting 3% PAA/NMP/THF solution by mass fraction onto a 2 cm×5 cm glass slide, and then stored in a vacuum oven at 60 ℃ for 24 h to ensure that the solvent was completely evaporated. Subsequently, the thermally treated at 100,200 and 300 ℃ for each 1 h to obtain 6FDA-BAPS PI membranes.

1.2.3 Fabrication of 6FDA-BAPS PI hollow fiber membranes

Asymmetric 6FDA-BAPS PI hollow fiber membranes were fabricated by the dry-jet-wet spinning process. PAA/NMP/THF spinning solution was filtered and degassed before spinning using a homemade hollow fiber spinning device. The polymer solution was pressurized through a spinneret by N2at 0.3 MPa and the internal coagulation bath directly flows into the hollow part of the spinneret. Then the polymer solution went through a certain air gap and immersed in the external coagulant bath. These fibers were taken up by a roller at a free falling velocity and stored in a water bath for at least 20 h to remove residual solvent. The membranes were dried under vacuum and then underwent thermal imidization.

2 Results and discussion

2.1 Structure of PI

As shown in Fig.1, all the vibrational bands can be assigned according to the results reported previously[8].

Fig.1 FTIR spectra of 6FDA-BAPS PI

The characteristic bands of 6FDA-BAPS PI at 1 781,1 719,1 371 and 718 cm-1are assigned to CO asymmetric and symmetric stretch peaks, C—N stretch peak and bending vibrations of the imide ring respectively. No characteristic peak of PAA at 3 300-3 400 cm-1indicates completely thermal imidization. Besides 1 301, 1 146 and 1 100 cm-1are attributed to the absorption peak of OSO, C—F and C—O，respectively.

Assignments of each proton are also given in Fig.3 and agree well with the proposed molecular structure in Fig.2.

Fig.2 Structure formula of 6FDA-BAPS PI

Fig.3 1H-NMR spectra of PI

The chemical shift (δ)ofthepeaksatb,c,d,e,fandginFig.3correspondstothehydrogenpositiononthefunctionalgroups.Inaddition,NMRspectraofPAAshowthelinearunit—COOHabsorptionpeakatδof10.57and—NHCO—absorptionpeaksatδof6.55[9].NoprotonpeakofPAAisfoundinthe1H-NMRspectra,indicatingthatPAAcompletelytransformstoPIbythermalimidization.

2.2 Solubility of 6FDA-BAPS PI

The solubility properties of 6FDA-BAPS PI at room temperature and heating conditions are shown in Tab.1.

Tab.1 Solubility of 6FDA-BAPS membranes

Note:++ soluble at room temperature; + soluble on heating.

Attributing to the bulky trifluoromethyl moieties (—C(CF3)2—) in dianhydride and polar group —O— and —SO2— in diamine, the 6FDA-BAPS PI is soluble in NMP,N,N-dimethylacetamide(DMAc)andTHFatroomtemperatureandevensolubleindimethylsulfoxide(DMSO),dimethylformamide(DMF)atheatingconditions.

2.3 Thermal properties of PI

As shown in Fig.4, TGA measurement reveals 5% and 10% weight loss temperature in nitrogen atmosphere at 511 ℃ and 531 ℃, respectively, and the residual rate at 800 ℃ is 57%. The above data indicate that the obtained PI exhibits the high thermal stability and overcomes the shortcoming of the thermal property loss accompanied by the solubility improvement of traditional soluble PI.

Fig.4 Thermogravimetric curve of 6FDA-BAPS PI

2.4 Mechanical properties of film and hollow fiber membrane

As shown in Fig.5, the tensile strength of the dense film is up to 51.7 MPa, while the value of the hollow fiber membrane is 26.5 MPa.

Fig.5 Mechanical properties of 6FDA-BAPS PI1—PI film；2—PI hollow fiber

2.5 Morphology of PI hollow fiber membranes

The cross sections of the hollow fiber membranes are porous spongy shape, as shown in Fig.6a. This is attributed to the fact that the internal coagulant involves high content NMP with low solidification capacity, which causes the delayed phase separation. Furthermore, the external coagulant is of high content pure water with high solidification capacity which causes the instantaneous phase separation. All of these results in the needle-shaped pore structure in the cross sections of the hollow fiber membranes. Fig.6b are the SEM images of the inner surface which shows lacunosis porous structure. Fig.6c are the SEM images of the outer surface which are dense layers with defect partly.

Fig.6 SEM images of 6FDA-BAPS PI hollow fiber membranes

3 Conclusions

6FDA-BAPS PI containing trifluoromethyl, polyether and sulfonyl groups was prepared. The PI was soluble in polar aprotic solvents such as NMP, DMAc and THF, and was of high thermostability at 511 ℃ in nitrogen atmosphere. Hollow fiber membranes with dense skin layer and the loose and porous support layer were prepared by dry-jet-wet spinning process, and the tensile strength is 26.5 MPa.

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含砜基聚酰亞胺的合成及其中空纖維膜的制備甘從軍，江雪微，董 杰，趙 昕，張清華(東華大學(xué)材料科學(xué)與工程學(xué)院纖維材料改性國(guó)家重點(diǎn)實(shí)驗(yàn)室，上海 201620)摘要:以4,4′-(六氟異丙烯)二酞酸酐(6FDA)與4,4′-雙(4-氨基苯氧基)二苯砜(BAPS)為反應(yīng)單體，以N-甲基-2-吡咯烷酮(NMP)為溶劑，合成了聚酰胺酸(PAA)，將PAA溶液采用流延成膜的方法制備成薄膜；另外，將PAA溶液采用干-濕法紡絲工藝制得PAA中空纖維膜，再將PAA薄膜及其中空纖維膜在300 ℃左右的高溫?zé)岘h(huán)化制得6FDA-BAPS型聚酰亞胺(PI)膜。研究了6FDA-BAPS型PI及其中空纖維膜的結(jié)構(gòu)與性能。結(jié)果表明：所合成的6FDA-BAPS型PI為目標(biāo)產(chǎn)物，其在NNP、N,N-二甲基乙酰胺、四氫呋喃中具有良好的溶解性能。6FDA-BAPS型PI中空纖維膜外皮層致密、支撐層疏松多孔，該中空纖維膜具有較高的熱學(xué)性能和力學(xué)性能，在氮?dú)夥諊袩崾е?%的溫度為511 ℃，斷裂強(qiáng)度為26.5MPa。 關(guān)鍵詞：聚酰胺酸 聚酰亞胺 中空纖維膜 結(jié)構(gòu) 性能

TQ342+.731 Document code:A Article ID: 1001- 0041(2017)01- 0050- 04