曹高萍 程杰

摘 要：我國(guó)能源安全和環(huán)境污染形勢(shì)嚴(yán)峻，需要加快可再生能源發(fā)展，必須解決高效規(guī)模儲(chǔ)能技術(shù)才能實(shí)現(xiàn)穩(wěn)定供電。液流電池是規(guī)模蓄電的首選電源，在電網(wǎng)調(diào)峰、可再生能源發(fā)電的儲(chǔ)能等方面具有巨大的應(yīng)用前景，其開(kāi)發(fā)對(duì)于可再生能源高效利用具有重要的現(xiàn)實(shí)意義。為彌補(bǔ)全釩液流電池體系面臨的難題，該研究致力于研發(fā)液流電池新體系。該年度研究了全鉛液流電池、鋅鎳單液流電池、鋅溴液流電池及其材料性能，初步獲得了液流電池新體系的設(shè)計(jì)規(guī)律。鋅鎳液流電池，研究了鋅電極特性、正極衰減特性和電池模擬，研制了200Ah的電池單體，組成了38 V200 Ah和38 V600 Ah電池系統(tǒng)，充放電能量效率分別達(dá)到79%和74%以上（約1/3C）。研究了倍率性能提升方法，80 mA/cm2電流密度下能量效率可到80%。研究了鋅溴液流電池結(jié)構(gòu)和性能，驗(yàn)證了1 kW/2 kW·h電池系統(tǒng)，充放電能量效率達(dá)到75%（約20 mA/cm2）。研究了HBF4體系全鉛液流電池性能，采用亞氧化鈦、TaC等改進(jìn)了正極，循環(huán)穩(wěn)定性得到提高。申請(qǐng)了10項(xiàng)專(zhuān)利，發(fā)表了6篇文章。該研究基本完成了預(yù)期計(jì)劃內(nèi)容，獲得了重要的階段性結(jié)果，為后續(xù)的研究推進(jìn)和成果產(chǎn)出打下了較好基礎(chǔ)。

關(guān)鍵詞：電池 液流電池 鋅 電極

The Annual Technical Report of Study of High Efficiency New Flow Battery Systems

Cao Gaoping Cheng Jie

（Institute of Chemical Defense）

Abstract：Facing with situation of Serious environmental pollution and increasing tension in energy resources， it is necessary to accelerate the development of renewable energy. Thus efficient scale energy storage technology must be solved to achieve a stable power supply. Flow battery is the choice of scale battery for stabilizing renewable energy power supply， has great application prospect and important practical significance for renewable energy utilization. To make up the disadvantage faced by the vanadium flow battery system， our team is devoted to research and development of new flow battery systems. Zinc nickel flow battery， zinc bromide flow battery and all lead flow battery in HBF4 are studied by our team. The performance of these flow battery systems and the relationship with the activate materials are carefully investigated. For the zinc nickel Flow battery system， performance of zinc electrode and performance attenuation of the positive electrode have been studied， 200 Ah batteries are developed. A 38 V200 Ah and A 38 V600 Ah battery systems are formed and tested， charge and discharge energy efficiency of more than 79% and 74% are achieved，respectively （about 1/3 C rate）.A method for improvement of rate performance is proposed， and energy efficiency of 80% under current density of 80 mA/cm2 is obtained. For the zinc bromide flow battery system， structure and performance was studied，and a verified 1 kW/2kW·h battery system is structured； the charge and discharge energy efficiency of 75% （about 20 mA/cm2） is reached. For the all lead flow battery system， by adopting the Ti4O7， TaC and graphite as conductive materials for positive current collector，the cycle stability of the system was improved. Gratifying results， as 10 Chinese patents declared，6 paper published，have been achieved. This subject has basically completed the expected plan content， gained important results，and a good foundation has been laid for subsequent research new achievements.

Key Words：Battery； Flow battery； Zinc； Clectrode

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